Abstract:Biomass co-firing has emerged as one of the most technically mature and industrially viable pathways for decarbonizing coal-fired power generation while enabling the large-scale utilization of agricultural and forestry residues. It followed a coherent logic of fossil carbon substitution, synergistic pollutant control, biogenic carbon removal, and carbon chemical conversion. Three biomass co-firing configurations, including direct, indirect and parallel coupling were systematically examined, and their technical characteristics, operational applicability, and deployment boundaries were compared. The mechanisms by which biomass co-firing affected slagging and fouling, high-temperature corrosion, and combustion efficiency were analyzed, and the synergistic mitigation of SO2, NOx, particulate matter, and heavy metal emissions was evaluated. Particular emphasis was placed on recent advances in integrating biomass co-firing with carbon capture, utilization and storage (CCUS) to establish bioenergy with carbon capture and storage (BECCS), as well as on emerging strategies for the CO2 valorization of co-firing fly ash. A comparative analysis of policy frameworks in the European Union, the United Kingdom, the United States, Japan, and China was further conducted to identify opportunities and challenges pertinent to large-scale deployment in the Chinese context. The findings indicated that biomass co-firing was evolving from a fuel substitution strategy toward an integrated technological platform capable of delivering low-, near-zero-, and even negative-carbon electricity generation. Future research should prioritize sustainable biomass supply chains, safe operation at high co-firing ratios, system-level integration of BECCS, and high-value utilization of co-combustion by-products.